I know, it's not the very first discovery ever of water on the moon, but I found it interesting, at least.
Article: It's Official: Water Found on the Moon
Since man first touched the moon and brought pieces of it back to Earth, scientists have thought that the lunar surface was bone dry. But new observations from three different spacecraft have put this notion to rest with what has been called "unambiguous evidence" of water across the surface of the moon.
The moon remains drier than any desert on Earth, but the water is said to exist on the moon in very small quantities. One ton of the top layer of the lunar surface would hold about 32 ounces of water, researchers said.