You won't be finding non-Nintendo anime characters in any official SSB release, but now you can add Sailor Moon to SSBB. I found this Youtube video while searching for Sailor Moon and Super Smash Bros together in a Google search. There is a download link to a zip file that has the mod files, in the video's description on Youtube. You'll need to manually replace certain files in the game's ISO to apply the mod, then burn that modded version of the game to a DVD disk. The software you need to replace files in a Wii ISO is called WiiScrubber. You can find that easy enough with a Google search. I'm not gonna link you to any pirated ISOs, but if you've downloaded this kind of stuff before, you'll already know the websites that are likely to have the ISO.
Her model replaces the model of Princess Zelda, so at the character select screen, pick Zelda. You need to use softmodding on your Wii console before you can play any hacked games, or you'll need to use an emulator called Dolphin to play it on your computer.
This mod doesn't effect her Shiek model, so the Down+B transformation turns her into Shiek (not Super or Eternal Sailor Moon or something like that).
Check out the video I found that shows the mod here.
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